Valeurs limites et interdictions d’utilisation

pour des substances individuelles ou des classes de substances
dans le cadre des tests de moquettes

Cette page vous fournit des informations complémentaires sur les valeurs limites et les interdictions d’utilisation de substances spécifiques et de classes de substances dans la fabrication des revêtements de sol textiles.

Sécurité pour le consommateur et protection de l'environnement

Des procédés classiques d’analyse chimique ainsi que des tests modernes rapides sont utilisés pour contrôler les matières premières et le produit textile fini sur la teneur éventuelle d’un vaste éventail de substances nocives et polluantes. Parmi ces substances, on compte, entre autres, les métaux lourds, plastifiants, biocides, pesticides, POP classiques (polluants organiques persistants) ainsi que les substances extrêmement préoccupantes (SVHC) au regard du Règlement REACh.
Les substances ou groupes de substances listés ci-dessous font l’objet d’affectations de valeurs limites ou d’interdictions d’utilisation dans le système GUT.

Ces mesures sont non seulement dédiées à la sécurité des consommateurs, mais aussi à l’évitement d’impacts négatifs sur l'environnement. Les tableaux suivants fournissent des informations sur les différentes classes de polluants et sur les valeurs limites qui leur sont affectées.

Colorants et additifs de teinture (1 sur 7)

Colorants azoïques (Azo-Dyes) (5.2.1)

Tab. 5.2.1: Azo dyes & aromatic amines
Substance a)CAS-No.:GUT
ban on use
2-Methyl-5-nitroaniline a)99-55-8
2-Naphthylamine a)91-59-8
2,4-Diaminoanisol a)615-05-4
2,4-Diaminotoluene a)95-80-7
2,4,5-Trimethylaniline a)137-17-7
3,3'-Dichlorobenzidine a)91-94-1
3,3'-Dimethoxybenzidine a)119-90-4
3,3'-Dimethylbenzidine a)119-93-7
4-Aminoazobenzene a)60-09-3
4-Aminobiphenyl a)92-67-1
4-Chloro-2-methylaniline a)95-69-2
4-Chloroaniline a)106-47-8
4,4'-Diaminodiphenylmethane a)101-77-9
4,4'-Methylene-bis-(2-chloraniline) a)101-14-4
4,4'-Oxydianiline a)101-80-4
4,4'-Thiodianiline a)139-65-1
4,4’-Methylene-bis-(2-methylaniline) a)838-88-0
Benzidine a)92-87-5
o-Aminoazotoluene a)97-56-3
o-Anisidine a)90-04-0
o-Toluidine a)95-53-4
p-Cresidine a)120-71-8
Navy Blue 018112 b)(EC-No.: 405-665-4)
Aniline (cleavable) c)62-53-3
2,4-Xylidine c)95-68-1
2,6-Xylidine c)87-62-7
2-Naphthylammonium Acetate c)553-00-4
2,4-Diaminoanisole Sulfate c)39156-41-7
2,4,5-Trimethylaniline Hydrochloride c)21436-97-5
4-Chloro-o-toluidine Hydrochloride c)3165-93-3
Note:
Ban on use does not apply to listed substances only, but is always based on current state of knowledge.
a) Aromatic amines according to directive EC/61/2002 & REACH regulation EC/1907/2006 (Annex XVII, Nr. 43, App. 8)
b) Restricted azo dye listed in REACH Annex XVII, Nr. 43, App. 9
c) Other arylamines, cleavable arylamines, amine salts

Métaux lourds et plastifiants (2 sur 7)

Métaux lourds (Heavy Metals) (5.3)

Tab. 5.3: Schwermetalle / Heavy metals
Substanz
Substance
Abkürzung
Abbreviation
Grenzwert / Limit value
nach Aufschluss / after digestion
[mg/kg]
Grenzwert / Limit value
nach Extraktion / after extraction (in the eluate)
[mg/kg]
Blei / Lead(Pb)500.2
Chrom / Chromium(Cr)501
Chrom VI / Chromium VI(Cr VI)-not identifiable
Cadmium(Cd)400.1
Quecksilber/ Mercury(Hg)50not identifiable
Summe / Sum(Pb, Cr, Cd, Hg)100-
Antimon / Antimony(Sb) a)150 b)30
Arsen / Arsenic(As)-0.2
Nickel(Ni)-1
Kupfer / Copper(Cu)-50
Kobalt / Cobalt(Co)-1
Note:
- = no value available
not identifiable = not allowed to be detected
a) see also flame retardants
b) 150 mg Sb per 1 kg polyester fiber. Antimony is used a catalysts for polyester synthesis

Traitements biocides, agents conservateurs et pesticides (3 sur 7)

Traitements biocides (5.5.2)

Tab. 5.5.2: GUT- thresholds for biocides and in can-preservatives in carpets
Substanz
Substance name
Abkürzung
Abbreviation
CAS no.GUT limit value
[mg/kg carpet]
1,2-Benzisothiazol-3(2H)-oneBIT2634-33-5<40
1,2-Benzisothiazol-3(2H)-oneMBIT2527-66-4<10
1,2-Benzisothiazol-3(2H)-oneMIT2682-20-4<10
1,2-Benzisothiazol-3(2H)-oneCIT26172-55-4<5
1,2-Benzisothiazol-3(2H)-oneOPP90-43-7<10
1,2-Benzisothiazol-3(2H)-oneBNPD52-51-7<10
1,2-Benzisothiazol-3(2H)-oneDBDCB35691-65-7<20
1,2-Benzisothiazol-3(2H)-oneIPBC55406-53-6<20
Acrolein-107-02-8n.d.
Chlorocresol-59-50-7n.d.
Glutaral (Glutaraldehyde)-111-30-8n.d.
Hydrogen peroxide-7722-84-1n.d.
Peracetic acid-79-21-0n.d.
N-(trichloromethylthio)phthalimide (Folpet)-133-07-3
N,N′-methylenebismorpholine (MBM)-5625-90-1
Polyhexamethylene biguanide hydrochloride-27083-27-8
Note:
Ban on use does not apply to listed substances only, but is always based on current state of knowledge.
n.d. = not detectable

Formaldéhyde et traitements pour la protection de la laine (4 von 7)

Formaldéhyde (5.9)

Tab. 5.9: Formaldehyde & Formaldehyde releasing chemicals
Substanz
Substance
CAS-No.:GUT
Verwendungsverbot
ban on use
Formaldehyde50-00-0
Formaldehyde releasing chemicals-.-
Note:
Ban on use does not apply to listed substances only, but is always based on current state of knowledge.
-.- = more than one CAS-No. / substances group

Retardateurs de flammes et HAP (5 sur 7)

Retardateurs de flammes (5.11)

Tab. 5.11: Flame retardants
Substanz
Substance
Abkürzung
Abbreviation
CAS-No.:GUT
Verwendungsverbot
ban on use
Polybrominated biphenylsPBBs a)59536-65-1
Polybrominated biphenyl ethersPBDEs b)-.-
HexabromocyclododecanesHBCDDs c)25637-99-4
Tris-(2,3-dibrompropyl)phosphateTRIS126-72-7
Tris-(aziridinyl)-phosphinoxideTEPA545-55-1
Chlorinated paraffinsCPs d)-.-
Antimony trioxideSb2O31309-64-4
Antimony pentoxideSb2O51314-60-9
Tris-(2-chloroethyl)phosphateTCEP115-96-8
TrixylylphosphateTXP25155-23-1
Tris-(1,3-dichloro-2-propyl)phosphateTDCPP13674-87-8
Tris(2-chloro-1-methylethyl) phosphateTCPP13674-84-5
Triphenyl phosphate TPP115-86-6
Boric acid-10043-35-3
Diboron trioxide-1303-86-2
Tetraboron disodium heptaoxide, hydrate-12267-73-1
Disodium tetraborate, anhydrous-1330-43-4
Orthoboric acid, sodium salt-13840-56-7
Disodium tetraborate decahydrate-1303-96-4
Disodium tetraborate Pentahydrate-12179-04-3
Disodium octaborate-12008-41-2
2,2-Bis(bromomethyl)propane-1,3-diolBBMP3296-90-0
Bis-(2,3-dibromopropyl)phosphateBIS5412-25-9
Tetrabromobisphenol ATBBPA79-94-7
Tri-o-cresylphosphat-78-30-8
Note:
Ban on use does not apply to listed substances only, but is always based on current state of knowledge.
-.- = more than one CAS-No. / substances group

a) PBBs = e.g. (Monobromodiphenyl (MBB), Dibromodiphenyl (diBB), Tribromodiphenyl (triBB), Tetrabromodiphenyl (tetraBB), Pentabromodiphenyl (pentaBB), Hexabromodiphenyl (hexaBB), Heptabromodiphenyl (heptaBB), Octabromodiphenyl (octaBB), Nonabromodiphenyl (nonaBB), Decabromodiphenyl (decaBB)

b) PBDEs = e.g. Monobromodiphenyl ether (MBDE), Dibromodiphenyl ether (diBDE), Tribromodiphenyl ether (triBDE), Tetrabromodiphenyl ether (tetraBDE), Pentabromodiphenyl ether (pentaBDE), Hexabromodiphenyl ether (hexaBDE), Heptabromodiphenyl ether (heptaBDE), Octabromodiphenyl ether (octaBDE), Nonabromodiphenyl ether (nonaBDE), Decabromodiphenyl ether (decaBDE)

c) HBCDDs = α-Hexabromocyclododecane (α-HBCDD), β-Hexabromocyclododecane (β-HBCDD), γ-Hexabromocyclo-dodecane (γ-HBCDD), Hexabromocyclododecane (HBCD)

d) CCPs = Short chain chlorinated paraffins, C10-13 (SCCPs), Short chain chlorinated paraffins, C12-13 (SCCPs), Medium chain chlorinated paraffins, C14-17 (MCCPs)

Substances perfluorées (6 sur 7)

Produits chimiques perfluorés (5.14)

Tab. 5.14: (Per-)fluorinated alkylated substances and their salts
Substanzen
Substance
Abkürzungeen
Abbreviation
CAS-No.:GUT
Verwendungsverbot
ban on use
Perfluorooctanesulfonic acidPFOS1763-23-1ban on use
PerfluorooctanesulfonamidePFOSA754-91-6ban on use
Heptadecafluorooctanesulfonyl fluoridePFOSF/POSF307-35-7ban on use
Heptadecafluoro-N-methyloctanesulphonamideN-Me-FOSA31506-32-8ban on use
N-Ethylperfluorooctane-1-sulfonamideN-Et-FOSA4151-50-2ban on use
Heptadecafluoro-N-(2-hydroxyethyl)-N-methyloctanesulphonamideN-Me-FOSE24448-09-7ban on use
N-Ethyl-N-2-hydroxyethyl perfluorooctansulfulfonamideN-Et-FOSE1691-99-2ban on use
Perfluorooctanoic acidPFOA335-67-1ban on use
Perfluoroheptanoic acidPFHpA375-85-9ban on use
Perfluorononanoic acidPFNA375-95-1ban on use
Perfluorodecanoic acidPFDA335-76-2ban on use
Perfluoroundecanoic acidPFUdA2058-94-8ban on use
Tricosafluorododecanoic acidPFDoA307-55-1ban on use
Perfluorotridecanoic acidPFTrDA72629-94-8ban on use
Perfluorotetradecanoic acidPFTeDA376-06-7ban on use
Heptafluorobutyric acidPFBA375-22-4ban on use
Perfluoropentanoic acidPFPeA2706-90-3ban on use
Undecafluorohexanoic acidPFHxA307-24-4ban on use
Perfluoro-3,7-dimethyloctanoic acidPF-3,7-DMOA172155-07-6ban on use
Perfluorobutanesulfonic acidPFBS375-73-5ban on use
Perfluorohexane-1-sulphonic acidPFHxS355-46-4ban on use
Perfluoroheptane-1-sulphonic acidPFHpS375-92-8ban on use
Henicosafluorodecanesulphonic acidPFDS335-77-3ban on use
7H-Dodecafluoroheptanoic acid7HPFHpA1546-95-8ban on use
1,1,2,2-Perfluorodecanoic acid4HPFUnA34598-33-9ban on use
1,1,2,2-Perfluorooctanesulfonic acid1,1,2,2-PFOS27619-97-2ban on use
1,1,2,2-Perfluorohexan-1-ol4:2 FTOH2043-47-2ban on use
1,1,2,2-Perfluoroctan-1-ol6:2 FTOH647-42-7ban on use
1,1,2,2-Perfluordecan-1-ol8:2 FTOH678-39-7ban on use
1,1,2,2-Perfluordodecan-1-ol10:2 FTOH865-86-1ban on use
1,1,2,2-Perfluorooctyl acrylate6:2 FTA17527-29-6ban on use
1,1,2,2-Heptadecafluorodecyl acrylate8:2 FTA27905-45-9ban on use
1,1,2,2-Tetrahydroperfluorododecyl acrylate10:2 FTA17741-60-5ban on use
Note:
Ban on use does not apply to listed substances only, but is always based on current state of knowledge.

Fibres inorganiques, nitrosamines et autres substances (7 sur 7)

Fibres inorganiques (5.13)

Tab. 5.13: Inorganic fibres (asbestos)
SubstanceCAS-No.:GUT
ban on use
Actinolite77536-66-4ban on use
Amosite12172-73-5ban on use
Anthrophyllite77536-67-5ban on use
Chrysotile12001-29-5ban on use
Crocidolite12001-28-4ban on use
Tremolite77536-68-6ban on use
Note:
Ban on use does not apply to listed substances only, but is always based on current state of knowledge.